NASA Finds Ingredient of Household Plastic In Space

By  //  October 1, 2013

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propylene found on Saturn's moon Titan

ABOVE VIDEO: With a thick atmosphere, clouds, a rain cycle and giant lakes, Saturn’s large moon Titan is a surprisingly Earthlike place. But unlike on Earth, Titan’s surface is far too cold for liquid water – instead, Titan’s clouds, rain, and lakes consist of liquid hydrocarbons like methane and ethane (which exist as gases here on Earth). When these hydrocarbons evaporate and encounter ultraviolet radiation in Titan’s upper atmosphere, some of the molecules are broken apart and reassembled into longer hydrocarbons like ethylene and propane.

NASA.gov – NASA’s Cassini spacecraft has detected propylene, a chemical used to make food-storage containers, car bumpers and other consumer products, on Saturn’s moon Titan.

Titan-388

A small amount of propylene was identified in Titan’s lower atmosphere by Cassini’s Composite Infrared Spectrometer (CIRS). (NASA.gov image)

This is the first definitive detection of the plastic ingredient on any moon or planet, other than Earth.

A small amount of propylene was identified in Titan’s lower atmosphere by Cassini’s Composite Infrared Spectrometer (CIRS). This instrument measures the infrared light, or heat radiation, emitted from Saturn and its moons in much the same way our hands feel the warmth of a fire.

Propylene is the first molecule to be discovered on Titan using CIRS. By isolating the same signal at various altitudes within the lower atmosphere, researchers identified the chemical with a high degree of confidence. Details are presented in a paper in the Sept. 30 edition of the Astrophysical Journal Letters.

Conor Nixon

Conor Nixon

“This chemical is all around us in everyday life, strung together in long chains to form a plastic called polypropylene,” said Conor Nixon, a planetary scientist at NASA’s Goddard Space Flight Center in Greenbelt, Md., and lead author of the paper.

“That plastic container at the grocery store with the recycling code 5 on the bottom — that’s polypropylene.”

CIRS can identify a particular gas glowing in the lower layers of the atmosphere from its unique thermal fingerprint. The challenge is to isolate this one signature from the signals of all other gases around it.

“This chemical is all around us in everyday life, strung together in long chains to form a plastic called polypropylene. That plastic container at the grocery store with the recycling code 5 on the bottom — that’s polypropylene.” said Conor Nixon, a planetary scientist at NASA’s Goddard Space Flight Center in Greenbelt, Md., and lead author of the paper.

The detection of the chemical fills in a mysterious gap in Titan observations that dates back to NASA’s Voyager 1 spacecraft and the first-ever close flyby of this moon in 1980.

Voyager identified many of the gases in Titan’s hazy brownish atmosphere as hydrocarbons, the chemicals that primarily make up petroleum and other fossil fuels on Earth.

On Titan, hydrocarbons form after sunlight breaks apart methane, the second-most plentiful gas in that atmosphere. The newly freed fragments can link up to form chains with two, three or more carbons. The family of chemicals with two carbons includes the flammable gas ethane. Propane, a common fuel for portable stoves, belongs to the three-carbon family.

Voyager detected all members of the one- and two-carbon families in Titan’s atmosphere. From the three-carbon family, the spacecraft found propane, the heaviest member, and propyne, one of the lightest members. But the middle chemicals, one of which is propylene, were missing.

PROPYLENE FOUND AS A RESULT OF CIRS DATA

As researchers continued to discover more and more chemicals in Titan’s atmosphere using ground- and space-based instruments, propylene was one that remained elusive. It was finally found as a result of more detailed analysis of the CIRS data.

Michael Flasar

Michael Flasar

“This measurement was very difficult to make because propylene’s weak signature is crowded by related chemicals with much stronger signals,” said Michael Flasar, Goddard scientist and principal investigator for CIRS.

“This success boosts our confidence that we will find still more chemicals long hidden in Titan’s atmosphere.”

Cassini’s mass spectrometer, a device that looks at the composition of Titan’s atmosphere, had hinted earlier that propylene might be present in the upper atmosphere. However, a positive identification had not been made.

CASSINI-HUYGENS IS A COOPERATIVE PROJECT

“I am always excited when scientists discover a molecule that has never been observed before in an atmosphere,” said Scott Edgington, Cassini’s deputy project scientist at NASA’s Jet Propulsion Laboratory (JPL) in Pasadena, Calif.

Scott Edgington

Scott Edgington

“This new piece of the puzzle will provide an additional test of how well we understand the chemical zoo that makes up Titan’s atmosphere.”

The Cassini-Huygens mission is a cooperative project of NASA, the European Space Agency and the Italian Space Agency. JPL manages the mission for NASA’s Science Mission Directorate in Washington. The CIRS team is based at Goddard.

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